It all has to do with the carbon:nitrogen ratio. the decomposers synthesize enzymes to break down materials, enzymes are protein based and require nitrogen to be produced. So a c:N ratio of 25:1 or better is needed for a decent heat up. The steam produced is rich in ammonia, which is notrogen based so the steam is venting of some nitrogen to the atmosphere, but it probably happens in a slower compost pile as well, just not so visably. This is also why adding carbon rich and nitrogen deficient organics to the soil can cause a period of nitrogen lockout. the decomposers in the soil borrow the N to sythesize enzymes and they are temporarily not available for the plants. No biggie though, just give it a few weeks to break down or add a high N fertilizer when you incorporate a carbon rich material.