While Rotenone is "natural" and all that, it is considered really hazardous to use. It is especially deadly to fish if it gets washed into the stream/river water system. Most organic operations now consider it too dangerous to use so it is not approved by them to be organic though it used to be high on their lists.
It's possible the government may have even outlawed it for use as a pesticide, I don't know about that. But I'm pretty sure it is still used to kill fish, say trash fish in a body of water if you are going to restock it with a preferred species of fish.