I was thinking of you peteyfoozer when I read this paper on using vinegar as a herbicide in garlic fields:
For the past several years I have been using vinegar to kill bindweed in a massive patch of English Ivy on a steep slope; the vinegar knocks back the weedy morning glory, but has no effect on the waxy ivy leaves. I can spray it with reckless abandon and the results have been encouraging. Good chance that vinegar could torch your hollyhocks too-- and for the very small cost of purchasing a few gallons of vinegar I think it would be worth a try.
My suggestion would be to spray when the plants are nice and stressed, on a warm day with no wind. Ideally there should be several days of dry weather both before and after spraying, as rainy weather could wash off the vinegar and re-hydrate the plants. If you could hit the plants just as they begin to send up flower stalks that would be a bonus, as that is when they have committed all of their energy to above ground pursuits. If you use a tank sprayer you could spray the leaves without bending.
I like to spray the plants in the morning, and then again later in the day when it is really hot out. Coat the leaves with a fine spray as best you can. If possible follow up with another spray after a week or so. The plant may take several weeks to show signs of decline, which is normal. Field bindweed takes several applications before it dies, sending up new growth that I hit multiple times until it succumbs. Maybe this could work on holly hocks too.
By the way, there are several different vinegar available for purchase. I try to get the pickling vinegar, which is a little stronger than regular white vinegar. There is also a more acidic version that is used for household cleaning; around here it is far more expensive than the pickling one, so not worth the extra expense in my opinion. After you fill the tank be sure to add a little dish soap to increase the viscosity; this will help the solution stick to the leaves.